1,4-Butanediol

    • Product Name: 1,4-Butanediol
    • Chemical Name (IUPAC): Butane-1,4-diol
    • CAS No.: 110-63-4
    • Chemical Formula: C4H10O2
    • Form/Physical State: Liquid
    • Factroy Site: Yuanchuang Guojilanwan Creative Park, Huoju Road, Hi-Tech Zone, Qingdao, China
    • Price Inquiry: sales3@ascent-chem.com
    • Manufacturer: Shandong Hualu-Hengsheng Chemical Co., Ltd
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    Specifications

    HS Code

    789457

    Chemical Name 1,4-Butanediol
    Cas Number 110-63-4
    Molecular Formula C4H10O2
    Molecular Weight 90.12 g/mol
    Appearance Colorless, viscous liquid
    Odor Practically odorless
    Melting Point 20.1 °C
    Boiling Point 230 °C
    Density 1.017 g/cm³ at 20 °C
    Solubility In Water Miscible
    Flash Point 121 °C
    Refractive Index 1.445 at 20 °C

    As an accredited 1,4-Butanediol factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Application of 1,4-Butanediol

    Purity 99.5%: 1,4-Butanediol with purity 99.5% is used in high-performance polyurethane production, where it ensures superior mechanical strength and flexibility.

    Viscosity grade low: 1,4-Butanediol with low viscosity grade is used in solvent formulations, where it enables rapid blending and uniform consistency.

    Molecular weight 90.12 g/mol: 1,4-Butanediol with molecular weight 90.12 g/mol is used in polyester resin synthesis, where it contributes to optimal polymer chain formation.

    Melting point 20.1°C: 1,4-Butanediol with a melting point of 20.1°C is used in plasticizer manufacturing, where it provides stable processing at ambient temperatures.

    Stability temperature 230°C: 1,4-Butanediol with stability temperature of 230°C is used in thermoplastic elastomer applications, where it offers enhanced thermal durability.

    Water content ≤0.1%: 1,4-Butanediol with water content ≤0.1% is used in electronic-grade applications, where it guarantees low conductivity and high electrical insulation.

    Color APHA ≤10: 1,4-Butanediol with color APHA ≤10 is used in optical-grade polymers, where it ensures high purity and colorless end products.

    Hydroxyl value 1245 mg KOH/g: 1,4-Butanediol with hydroxyl value 1245 mg KOH/g is used in coating formulations, where it improves reactivity and crosslinking density.

    Acid value ≤0.05 mg KOH/g: 1,4-Butanediol with acid value ≤0.05 mg KOH/g is used in pharmaceutical intermediates, where it reduces impurities and enhances product safety.

    Particle size ≤10 μm: 1,4-Butanediol with particle size ≤10 μm is used in specialty adhesives, where it allows fine dispersion and strong bonding characteristics.

    Packing & Storage
    Packing 1,4-Butanediol is packaged in a 25-liter high-density polyethylene drum, sealed securely, with clear hazard and identification labeling.
    Container Loading (20′ FCL) **Container Loading (20′ FCL):** 1,4-Butanediol is typically loaded in 20′ FCL with about 17-20 metric tons in steel drums or IBCs.
    Shipping 1,4-Butanediol is shipped in tightly sealed, corrosion-resistant containers such as steel drums or HDPE tanks. It should be stored in a cool, well-ventilated area, away from sources of ignition and incompatible substances. Ensure proper labeling and documentation in compliance with transportation regulations, as it is considered a regulated substance.
    Storage 1,4-Butanediol should be stored in a tightly closed container in a cool, dry, well-ventilated area, away from heat, sparks, and open flames. Keep the storage area free from incompatible substances such as strong oxidizers. Use corrosion-resistant containers and avoid prolonged exposure to air and moisture. Ensure proper labeling and provide secondary containment to prevent leaks or spills.
    Shelf Life 1,4-Butanediol typically has a shelf life of 2 years when stored properly in tightly closed containers, under cool, dry conditions.
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    More Introduction

    1,4-Butanediol: A Closer Look From the Manufacturer’s Bench

    Shaping Industry With 1,4-Butanediol

    Decades on the line have shown us manufacturing never stays still. Change isn’t just part of the story—it drives every batch, controls every reaction, and shapes every deal. 1,4-Butanediol (BDO) remains a perfect example of a material that keeps in step with what industries actually need. More than a feedstock, BDO acts like a molecular bridge, letting us unlock value for plastics, fibers, solvents, biodegradable polymers, and countless other specialty chemicals. Our direct production of BDO—streamlined and controlled from raw materials to finished liquid—delivers consistency that downstream processors rely on.

    Molecular Formula and Key Features

    Chemically labeled as C4H10O2, 1,4-Butanediol appears as a clear, colorless, and slightly oily liquid. Our lot purity averages consistently exceed 99.5%, taken straight from routine quality checks. BDO is fully miscible in water, low in toxicity compared to many alternatives, and offers a faint, sweet odor that reveals itself in plant filling rooms. Because BDO’s hydroxyl groups sit on opposite ends of the molecule, it brings versatility for further synthetic reactions, notably producing 2,5-tetrahydrofuran, polyurethanes, and polybutylene terephthalate (PBT).

    From the Reactor—Our Model and Approach

    Not all BDO comes from the same lineage. We use a continuous process, hydrogenating maleic anhydride or succinic acid, depending on feedstock availability and energy pricing. Reactor temperature control and catalyst quality both shape our yield and selectivity. Tight process controls minimize side products like gamma-butyrolactone and tetrahydrofuran, which require further separation during downstream purification. Operators track temperature, pressure, and hydrogen flow rates each shift—no digital reading matches the intuition built over years of running the plant.

    Final product from our finishing tanks undergoes filtration and distillation, stripping out water, color bodies, and residuals. By packing glass-lined vessels for storage and loading, we avoid oxidation or off-smells that can plague plastic containers. Inspection teams sample each outgoing batch, using both infrared spectroscopy and wet chemical methods, checking for unwanted methanol, heavier glycols, or off-spec haze. No shipment leaves unless it passes all specifications for color, clarity, pH, and methanol-by-gas-chromatograph.

    Specifications and Certifications Matter

    Buyers request technical or high-purity grades, depending on end use. The technical grade fits polymer synthesis well, while high-purity grades target demanding solvent and electronics applications. Our most recent batch results came back with water content below 100 ppm and color at <2 APHA—benchmarks that demand real effort to achieve. Whether we’re prepping drums for delivery to a coatings plant or loading a tank wagon for a fiber producer, every operator here knows the value of rigorous documentation. Our facilities operate under ISO 9001 and strive to stay in step with REACH and other regulatory frameworks, frequently updating records and processes after both internal audits and outside inspections.

    Lab reports don’t just satisfy regulatory obligations; they protect downstream equipment, prevent polymer yellowing, and keep final products on end-user shelves. Impurities, even at trace levels, can trigger unwanted side reactions—problems we’ve chased down in more than one customer troubleshooting session.

    What Sets Our 1,4-Butanediol Apart

    We’ve worked shoulder to shoulder with processing customers who’ve been burned in the past by off-brand BDO, loaded with water or contaminated by unexpected byproducts. Lumpy batches lead to gummed-up reactors, downtime, and waste. Our focus remains on hitting a repeatable purity profile so every drum performs the same as the last, even when raw material costs fluctuate or feedstock supply lines tighten. We train operators on both process control and sensory checks so that columns run steady and tanks hold only spec product.

    Physical handling matters, too. Because BDO remains sensitive to air and humidity, we maintain inert gas blankets and use moisture-proof seals during storage and loading. Returns from our customers often involve unused product that’s spent months in storage. Unlike lesser products, properly handled material from our lines resists picking up acidity or degradation signals, even after lengthy storage—one reason repeat clients remain with us year-over-year.

    Major Uses of 1,4-Butanediol in Modern Industry

    Most talk about BDO centers on its use in making polybutylene terephthalate (PBT), a resilient engineering plastic. But BDO does more than feed this market. It forms the backbone for manufacturing tetrahydrofuran (THF), used for spandex fiber production and as a vital solvent in specialty pharmaceutical processes. Polyurethane systems, both in rigid foams and elastomers, tap BDO for chain extension and flexibility due to its bifunctional nature. We see coatings firms ordering BDO to serve as a reactive diluent, leveraging the diol’s low volatility and strong compatibility with isocyanate chemistries. Solvent manufacturers buy batches designed for use in cleaning agents, ink production, and adhesive formulations, seeking the odor, solvency, and hygroscopic properties that BDO brings.

    As biodegradable plastics gain a foothold, succinic acid and BDO together form polybutylene succinate (PBS), supporting customers pushing for greener, compostable packaging. We see demand cycles run up from both established names in packaging and newer players offering competitive bioplastics. The functional range of BDO underlies its reliability across shifting industry trends—you don’t have to look further than the wide range of customers we serve, from auto and electronics to cosmetics formulators.

    1,4-Butanediol Versus Alternative Diols and Solvents

    Plenty of neighboring molecules crowd the industrial diol market, but not all check the boxes BDO does. Manufacturers sometimes weigh BDO against 1,3-butylene glycol, ethylene glycol, and propylene glycol. Experience shows that switching from BDO to one of these often shrinks process flexibility. BDO’s longer hydrocarbon chain gives it a melting point near 20°C, so it remains liquid just above room temperature—easing drum handling and mixing on the plant floor, especially compared to the solid, waxy state of shorter diols. Its higher boiling point (around 230°C) resists evaporation in heated batch tanks, unlike common glycols that can drift off during solvent recovery.

    In polyester production, using ethylene glycol instead of BDO sparks differences in plastic toughness and flexibility. PBT made with BDO outperforms, offering better heat and chemical resistance. Polyurethanes leveraging BDO rather than glycerol or trimethylolpropane form tougher, more elastic foams—our technical partners routinely tweak their formulations with side-by-side trials to balance softness and durability.

    Safety and environmental standards further distinguish BDO. While methanol and dichloromethane remain common solvents in many applications, their health risks and disposal costs run higher. BDO’s low acute toxicity and minimal vapor pressure keep operators and the plant air safer. Handling BDO, we rely on splash protection, ventilation, and leak detection, but the risk profile fits well in tightly run modern plants.

    Reliability Underpins Repeat Business

    Customers who buy direct from a manufacturer ask the kind of questions traders or resellers often can’t answer: What’s the real water content? Was this batch made with high-sulfur feedstock? How long was it in storage before dispatch? Our own delivery staff can stand behind their answers, because they watched the batch produced, sampled it, and managed the loading operation—all under one roof. This difference keeps small and medium producers, who often work without vast labs or support teams, coming back for supply.

    One story stands out: a polyurethane foam plant we support faced recurring bubble formation in their final product. Analysis traced the problem to a contaminated BDO shipment sourced from an importer, loaded weeks before and held under poor conditions. After switching to our tank deliveries, and after retraining on storage protocols, foam quality stabilized, downtime fell, and warranty calls dropped significantly.

    Quality, Traceability, and Environmental Commitment

    Today’s buyers track more than price and lead time. Market demand has forced a higher bar for quality traceability, responsible sourcing, and environmental stewardship. We face questions about raw material origins nearly weekly. We respond by integrating batch-level tracking—every drum, tank, or shipment can be mapped to its feedstock lot, production shift, and QA record. We face regular spot-audits not just from regulators but from our European and American buyers, who value transparency as much as our product spec sheet.

    Sustainability isn’t just for presentation. A steady portion of our plant’s energy comes from cogeneration, cutting greenhouse emissions and waste heat. Waste streams—particularly process water—are treated, recycled, and monitored for residual contaminants before discharge or reuse in facility utilities. Our engineering group continues to evaluate bio-based feedstocks for BDO, though pricing and technical maturity still lag petrochemical counterparts. Once these alternatives hit consistent yields and quality, we expect buyer interest to solidify beyond the small pilot orders we now see.

    Health and Safety: Hands-On Experience Counts

    Anyone handling BDO regularly knows spills and leaks are a reality, not a hypothetical. Plant floor protocols treat BDO as a moderate eye and skin irritant, calling for straightforward PPE—gloves, splash goggles, boots. BDO vapors don’t pose the acute workplace hazard of many chlorinated or aromatic solvents, so ventilation remains manageable even on older lines. Every plant manager dreads fires; BDO’s high flash point offers more time to react than lower-boiling alcohols, reducing the odds of a flash fire during transfer or cleaning.

    We teach new operators to respect BDO’s reactivity with oxidizers and acids, but standard handling and cleaning routines usually keep risk low. Our storage and loading areas rely on spill containment, prompt cleanup, and training in basic first aid for accidental splashes—controls learned from long experience, not by reading data sheets or codes.

    Shipping and Storage—Practical Insights

    Shipping a bulk chemical like BDO sounds simple until you manage the unpredictable: weather delays, port congestion, customer tank readiness, or a rare but nagging container leak. Our facility ships by tank truck, ISO container, and drum, all carefully cleaned and purged of prior loads. BDO’s high density and viscosity slow pumping rates, so drivers and loaders count on well-maintained hoses, air seals, and pump unions to keep the flow moving.

    Inside customer plants, storage tanks need tight gasketing and dry nitrogen blankets to ward off water pickup and oxidation. We recommend regular sampling and cleaning—hard lessons learned from drums forgotten outside, where water absorption over a humid summer can start to degrade material by fall. Many buyers now ask for bulk BDO in insulated, food-grade tanks, especially those running continuous polymerization units. Clear troubleshooting lines, and prompt advice from plant veterans, make the difference between smooth operation and costly off-grade batches.

    Responding to Industry Trends—Opportunities and Risks

    BDO demand rises and falls with the health of the auto, construction, and technical textiles markets. We plan production schedules months in advance, but remain flexible for sudden surges or pauses. Downstream innovation also pushes our process capabilities: with advances in waterborne polyurethanes, new generations of spandex, and a focus on compostable polymers, customers place new demands on purity, consistency, and supply reliability. Rather than chase every temporary trend, our experience as manufacturers helps us pick which shifts to invest in, and which to watch mature before dedicating a line.

    Trade policy, regulatory changes, and evolving environmental standards also shape the risk landscape. Sourcing plant-based BDO from sugar fermentation has grown, but hydrogen cost and separation efficiency still tether widespread commercial use. We watch these developments and run pilot batches with early adopters, seeing what problems surface at scale before making bold claims or long-term commitments.

    Common Quality Issues—And How Manufacturers Solve Them

    No product run escapes the usual challenges—trace water, slight color shifts, or occasional yield dips. Seasoned operators know to watch for condensation risks, especially during early morning or rainy season loading. In-process testing and end-point analysis serve as stops on the road to final approval, catching any batch that drifts out of range. Color formation, especially trace yellowing at adjacent piping transitions, often points to a failed gasket or sticky valve, prompting a repair and resample.

    Methanol residues hover as another stubborn risk, sometimes creeping above target as catalyst beds wear down or raw material lots shift. Regular equipment cleaning, keeping fresh catalyst charge, and disciplined recalibration of analytical gear remain our first tools—strategies better learned by years on the plant floor than any training video.

    Customer Collaboration—The Difference Direct Manufacturing Makes

    Relying on importers or distribution middlemen may suit volume buyers, but nothing beats direct line-of-sight from the production vessel to the customer’s blend tank. Our technical staff field questions about adaptions in polymer recipes, contamination troubleshooting, and process adjustment—often spotting early signs of trouble before they bloom into major headaches. We loan insight to clients scaling up new applications or transitioning formulations, and share sample histories and lab reports to close the information gap for everyone along the chain.

    Through regular visits, calls, and real-time support, issues—such as controlling foam in spandex fiber spinning, or reducing haze in specialty solvent blends—receive practical solutions crafted from both manufacturer experience and a knowledge of what’s been tried before. Full traceability, direct accountability, and a real stake in the outcome separate dedicated BDO manufacturing from mere reselling.

    The Value of Consistency—A Manufacturer’s Perspective

    Consistency, batch after batch, means more than a number on a spec sheet. It shows up in the form of fewer reactor upsets, streamlined plant maintenance, easier troubleshooting, and end products that perform predictably on the market. We see these results unfold through decades of operation, through the customer feedback that flows in, and through the patterns of repeat orders that support both sides of the partnership.

    BDO will keep shaping the backbone of new resin systems, solvents, and specialty polymers. But only those who produce, test, and ship the material understand every step it travels and every risk it faces, from the first raw material delivery to the last gallon pumped into the customer’s tank. Direct experience, rigorous control, and open channels with processing partners combine to make a difference that endures far beyond the point of sale.